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About Stainless Steel


What is Stainless Steel? What are its types?

Stainless Steels

Stainless steel is an iron alloy.It should contain min 10.5% Cr and max 1.2% C element. The importance of the Cr element used in stainless steel is that it forms an oxide layer (Cr2O3) on the surface of the material and thus protects the material from oxygen.

The Cr and passivation rate in stainless steel determines the stainless quality of the steel.

The oxide layer formed on the surface of the material is too thin to be seen with the eye and is waterproof.

Types of Stainless Steel

  • Ferritic Stainless Steels
  • Austenitic Stainless Steels
  • Martensitic Stainless Steels
  • Ferritic-Austenitic (Duplex) Stainless Steels

Ferritic Stainless Steels

This type of stainless steels contains low carbon and 12-18% Cr. They provide moderate corrosion resistance. They cannot be easily shaped like austenitic steels. They exhibit magnetic properties and their resistance cannot be increased by heat treatment.

Certain areas of usage: Kitchenware, decorative applications, automobile chassis parts, exhaust elements, hot water tanks…

Martensitic Stainless Steels

If stainless steels with an austenitic structure at high temperatures and a Cr content of more than 0.1% are quenched, the austenitic structure turns into a martensitic structure. Martensitic structure is a structure with high strength and hardness, but its brittleness is also relatively higher. Since excessive hardness will also cause brittleness, its hardness can be reduced somewhat by annealing during the manufacturing phase and its strength can be brought to the desired level.

They possess medium level of corrosion resistance, heat treatment can be applied to them, they are magnetic and possess low capacity of being welded.

Certain areas of usage: Knives, surgical instruments…

Austenitic Stainless Steels

When nickel is added to stainless steel, an austenitic structure is obtained at room temperature. The austenitic structure obtained at room temperature provides the materials with the opportunity to be plastically shaped, high strength and good corrosion resistance. Their mechanical strength cannot be increased by heat treatment, but it can be increased by cold working. These types of steels, which are normally non-magnetic, can also gain partial magnetic properties with cold working.

They possess the capacity to be fine welded, they are hygienic, their impact resistance at low temperature levels is fine.

Certain areas of usage: Machinery and manufacturing industry, architectural applications, food processing equipment…

Ferritic – Austenitic (Duplex) Stainless Steels

This type of steels have both ferritic and austenitic structures at the same time. Since they have these two structures together, they provide both high strength, hardness and toughness properties at the same time. Fatigue resistance in corrosive environments is very good. They have good weldability and forming properties.

Certain areas of usage: In marine and salt water environments, in the petrochemical sector, in heat exchanger manufacturing…

Resistance of Stainless Steels to Acids

Stainless steels are generally considered to be resistant to acids. However, this issue is closely related to the type of acids, their concentration, the type of steel and the ambient temperature. For example, although type 904 stainless steels are resistant to high concentrations of sulfuric acids at room temperature, grade 304 stainless steels cannot withstand even low concentrations.

While 304L and 430 quality stainless steels are resistant against nitric acid, hydraulic acid can damage any type of stainless steel.

Resistance of Stainless Steels to Bases

300 Series stainless steels can resist bases at high concentrations. However, the same series of stainless steels are not resistant to “Sodium Hydroxide” which is a stronger base type.

The point to be noted here is that stainless steel should never be considered as rust-proof. If each type of stainless steel is used in places that are suitable for its own properties, it can be used for a long time without wear. However; if it is used in places that are not suitable for its own chemical and mechanical resistance, it loses its stainlessness feature.

Magnetic Properties of Stainless Steels

Ferritic and martensitic stainless steels are magnetic.
Austenitic stainless steels are not magnetic.
Austenitic stainless steels that are cold formed gain some magnetic properties.
Burdan da anlaşılacak şey şudur;
What can be understood from this is that if an austenitic stainless steel holds a magnet, it means that it has been cold formed.

Cleaning

Stainless steels should be cleaned before use. Contaminated deposits on the surfaces of such steels can cause the stainless steel to rust in the future. Cleaning can be done with a clean cloth and water or special cleaning solutions. However, the point to be considered here is to remove water or solvent residues from the surface after cleaning. Because water droplets on the surface can locally rust the steel.

In addition, during storage, stainless steels should be kept out of contact with the soil and should be kept away from places where carbon steels are stored or processed. Because when any carbon steel shaving gets into contact with stainless steel, stainless steel can start to rust.

For example; if purchased stainless tubes are stored on the ground in a way that they will be exposed to rain, some rainwater will accumulate inside the tubes, and if the wet parts of the tube are not dried in the following days, they will start to rust from the inner surface of the tube or from the contact areas where water remains.

Another example to be given regarding the rusting of stainless materials is as follows;

For instance, stainless steel tubes will be installed in a factory. During the installation phase, these tubes are integrated into a carrier skeleton when they are assemblied. The skeleton part that will carry the tubes is usually made of carbon steel material. Due to the nature of the assembly, stainless steel tubes will come into contact with the carbon steel carrier skeleton and will be used in that way. It is very important to take precautions regarding this issue. Because, if carbon steel is in contact with stainless steel, there will be an interaction between them and therefore rust will start to take place at the contact points. In the later stages, rust can increase and the tubes can reach the point of perforation. In order to prevent this issue, it is inevitable for the company performing the assembly to take certain precautions.

During assembly process, the carbon steel carrier frame and stainless steel tubes should never come into contact. Plastic materials can be placed on the contact points to prevent contact and avoid rust.

A common misconception in use is that this type of steel will never rust. If stainless steels are not stored in an isolated environment, they will rust after a certain period of time.

Naming of stainless steels as per standards

EN STANDARD STEEL NO. EN STANDARD STEEL NAME SAE UNS
1.4109 X65CrMo14 440A S44002
1.4112 X90CrMoV18 440B S44003
1.4125 X105CrMo17 440C S44004
1.4016 X6Cr17 430 S43000
1.4408 G-X 6 CrNiMo 18-10 316 S31600
1.4512 X6CrTi12 409 S40900
1.4310 X10CrNi18-8 301 S30100
1.4318 X2CrNiN18-7 301LN
1.4307 X2CrNi18-9 304L S30403
1.4311 X2CrNiN18-10 304LN S30453
1.4301 X5CrNi18-10 304 S30400
1.4948 X6CrNi18-11 304H S30409
1.4303 X5CrNi18-12 305 S30500
1.4841 X22CrNi2520 310 S31000
1.4845 X 5 CrNi 2520 310S S31008
1.4541 X6CrNiTi18-10 321 S32100
1.4878 X12CrNiTi18-9 321H S32109
1.4404 X2CrNiMo17-12-2 316L S31603
1.4401 X5CrNiMo17-12-2 316 S31600
1.4406 X2CrNiMoN17-12-2 316LN S31653
1.4432 X2CrNiMo17-12-3 316L S31603
1.4435 X2CrNiMo18-14-3 316L S31603
1.4436 X3CrNiMo17-13-3 316 S31600
1.4571 X6CrNiMoTi17-12-2 316Ti S31635
1.4429 X2CrNiMoN17-13-3 316LN S31653
1.4438 X2CrNiMo18-15-4 317L S31703
1.4362 X2CrNi23-4 2304 S32304
1.4462 X2CrNiMoN22-5-3 2205 S31803 / S32205
1.4501 X2CrNiMoCuWN25-7-4 J405 S32760
1.4539 X1NiCrMoCu25-20-5 904L N08904
1.4529 X1NiCrMoCuN25-20-7 N08926
1.4547 X1CrNiMoCuN20-18-7 254SMO S31254

Surface types of stainless steels

No. 0:Hot rolled, annealed
No. 1: Hot rolled, annealed and passivated
No. 2D: Cold rolled, annealed, cleaned with acid and passivated
No. 2B: Coll rolled, annealed, cleaned with acid and passivated (extra bright rolled)
No. 2BA: Cold rolled, bright annealed, cleaned with acid and passivated
No. 3: Mechanically rough machined surface
No. 4: Brushed surface
No. 5: Satin surface
No. 6: Matte surface
No. 7: Bright surface
No. 8: Mirror surface

Effect of Alloying Elements on Stainless Steel

CHROMIUM (Cr)
It is the most important element that gives stainless steel its stainless feature. As the % Cr amount increases, its stainless feature increases. Chromium element protects the steel against rusting with the passive oxide layer it forms on the surface of the steel. It has a strong ferrite-forming feature.

NICKEL (Ni)
It is added to stainless steels to give them an austenitic structure. By adding nickel to steel, steel brittleness decreases and thus it has a tough structure. It also increases resistance to acidic environments.

MOLYBDENUM (Mo)
It is added to increase mechanical strength and corrosion resistance.

COPPER (Cu)
It is added to slightly increase the formability of stainless steels and their resistance to acids.

MANGANESE (Mn)
It is added to increase the high temperature resistance of stainless steels. Manganese is also an austenitic-forming element and can be used instead of nickel.

SILICON (Si)
It is a ferrite-forming element. It increases the resistance of steel to oxidation. It enhances strength.

CARBON (C)
It increases the mechanical strength and hardness of steel. Excess carbon adversely affects the stainless property, plastic forming and weldability properties.

NITROGEN (N)
It is an austenite-forming element. It increases mechanical strength, but reduces the toughness of steel in ferritic steels.

TITANIUM (Ti)
It has a strong carbide-forming property and increases hardness. It is also used as deoxidant during steel production. It has a grain-refining effect.

Particulars to be Considered When Choosing Stainless Steel

When choosing a stainless steel type, it is important to make a choice that is suitable for where it is used. Price should also be taken into consideration when making a choice. However; if price is at the forefront of importance, it is likely to encounter problems in terms of use in the future.

If the place where the steel is used and the properties of the material to be purchased are correctly matched, the stainless steel to be purchased can be used for many years without encountering any problems.

If the supplied material is preferred because it is cheap, this may cost the consumer more in the future. For example, if 304 quality stainless steel is used instead of 316 quality stainless steel in a place where savings are required, although it may seem like savings are being made at first, choosing the wrong material can cause bigger problems in the future.

  • Properties to pay attention to ;
    • Corrosion resistance of material
    • Mechanical resistance of material
    • Physical properties of material
    • Surface features of material
    • Ambient temperature
    • Type of corrosive agents it will be used against.

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